有机碲化合物作为可控/活性自由基聚合的新型引发剂。功能化聚苯乙烯的合成及端基修饰。
Organotellurium compounds as novel initiators for controlled/living radical polymerizations. Synthesis of functionalized polystyrenes and end-group modifications.
作者信息
Yamago Shigeru, Iida Kazunori, Yoshida Ji Jun-ichi
机构信息
Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-8501, Japan.
出版信息
J Am Chem Soc. 2002 Mar 27;124(12):2874-5. doi: 10.1021/ja025554b.
PMID:11902869
Abstract
Polymer-end mimetic organotellurium compounds initiate controlled/living radical polymerization of styrene derivatives that allows accurate molecular weight control with defined end-groups. Transformations of the end-groups via radical and ionic reactions provide a variety of end-group modified polystyrenes.
摘要
聚合物端基模拟有机碲化合物引发苯乙烯衍生物的可控/活性自由基聚合，从而实现对分子量的精确控制以及端基的确定。通过自由基和离子反应对端基进行转化，可得到多种端基修饰的聚苯乙烯。
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