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Isotactic-b-syndiotactic stereoblock poly(methyl methacrylate) by chiral metallocene/Lewis acid hybrid catalysts.

作者信息

Bolig Andrew D, Chen Eugene Y-X

机构信息

Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523-1872, USA.

出版信息

J Am Chem Soc. 2002 May 22;124(20):5612-3. doi: 10.1021/ja025796b.

DOI:10.1021/ja025796b
PMID:12010014
Abstract

Stereoblock polymerization with chiral ansa-metallocene/strong Lewis acid hybrid catalysts capable of switching stereospecificity of the methyl methacrylate polymerization produces the highly stereoregular isotactic-b-syndiotactic stereoblock poly(methyl methacrylate).

摘要

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