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拉各斯都会区处理精炼石油产品设施附近土壤中总石油烃和重金属的测定

Determination of total petroleum hydrocarbons and heavy metals in soils within the vicinity of facilities handling refined petroleum products in Lagos metropolis.

作者信息

Adeniyi A A, Afolabi J A

机构信息

Department of Chemical Sciences, Lagos State University, Apapa, Nigeria.

出版信息

Environ Int. 2002 Apr;28(1-2):79-82. doi: 10.1016/s0160-4120(02)00007-7.

Abstract

This article discusses the determination of total petroleum hydrocarbons (TPH) and heavy-metal contamination in soils within areas of refined petroleum products handling in Lagos metropolis. Soil samples were collected randomly from two petrol stations, two auto-mechanic workshops, and a National Electric Power Authority (NEPA) station. Control samples were taken from two low-density residential areas. TPH were estimated gravimetrically following standard methods of TPH analysis, while the heavy metals were determined by atomic absorption spectrophotometry. Sites studied had higher levels of TPH and heavy metals compared to the control samples. For TPH, the petrol stations have mean values of 399.83+/-106.19 and 450.83 +/- 90.58 microg/g, respectively; mechanic workshops, 362.60 +/- 185.84 and 428.55 +/- 119.00 microg/g, respectively; while the NEPA station has 356.20 +/- 210.30 microg/g compared to the control mean of 26.63 +/- 4.58. It revealed that the improper handling of refined petroleum products are potential sources of soil contamination in the sampled sites. This is indicated by the statistically significant levels of TPH and heavy metals observed between the control samples and those collected from the petroleum products handling sites. Bioremediation using microorganisms and plants is recommended.

摘要

本文探讨了拉各斯大都市中精炼石油产品处理区域内土壤中石油总烃(TPH)的测定及重金属污染情况。从两个加油站、两个汽车修理车间和一个国家电力管理局(NEPA)站点随机采集土壤样本。对照样本取自两个低密度住宅区。TPH按照TPH分析的标准方法采用重量法进行估算,而重金属则通过原子吸收分光光度法测定。与对照样本相比,所研究的站点TPH和重金属含量更高。对于TPH,加油站的平均值分别为399.83±106.19和450.83±90.58微克/克;汽车修理车间分别为362.60±185.84和428.55±119.00微克/克;而NEPA站点为356.20±210.30微克/克,对照平均值为26.63±4.58。结果表明,精炼石油产品的不当处理是采样站点土壤污染的潜在来源。对照样本与从石油产品处理站点采集的样本之间TPH和重金属的统计显著水平表明了这一点。建议采用微生物和植物进行生物修复。

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