（二苄基亚砜-κO）双（1,3-二苯基丙烷-1,3-二酮-κ(2)O,O'）二氧铀（VI）
(Dibenzyl sulfoxide-kappa O)bis(1,3-diphenylpropane-1,3-dionato-kappa(2)O,O')dioxouranium(VI).
作者信息
Fun Hoong-Kun, Kannan S, Usman Anwar, Abdul-Razak Ibrahim, Chantrapromma Suchada
机构信息
X-ray Crystallography Unit, School of Physics, Universiti Sains Malaysia, 11800 USM, Penang, Malaysia.
出版信息
Acta Crystallogr C. 2002 Jul;58(Pt 7):m368-70. doi: 10.1107/s010827010200848x. Epub 2002 Jun 12.
In the title compound, [UO(2)(C(15)H(11)O(2))(2)(C(14)H(14)OS)], the U(VI) atom is coordinated by seven O atoms in a distorted pentagonal-bipyramidal geometry. Both diphenylpropane-1,3-dionate systems are nearly planar. The sulfoxide moiety is in a distorted tetrahedral geometry, while its two aromatic rings are nearly orthogonal to one another. The crystal packing is stabilized by two bifurcated hydrogen-bonding interactions involving both uranyl O atoms.
在标题化合物[UO₂(C₁₅H₁₁O₂)₂(C₁₄H₁₄OS)]中，U(VI)原子由七个O原子配位，呈扭曲的五角双锥几何构型。两个二苯基丙烷 - 1,3 - 二酮体系近乎平面。亚砜部分呈扭曲的四面体几何构型，而其两个芳环彼此近乎正交。晶体堆积通过涉及两个铀酰O原子的两个分叉氢键相互作用得以稳定。
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