Halcrow Malcolm A, Kilner Colin A
School of Chemistry, University of Leeds, Woodhouse Lane, Leeds LS2 9JT, England.
Acta Crystallogr C. 2002 Jul;58(Pt 7):m424-6. doi: 10.1107/s0108270102010053. Epub 2002 Jun 29.
The title compound, [CuI(C(17)H(21)N(5))] x CH(2)Cl(2), contains a tetracoordinate Cu(I) centre with an unusual distorted tetrahedral stereochemistry, which has also been observed in other Cu(I) complexes containing this tridentate ligand. This distortion is probably a result of intermolecular steric contacts between the I(-) ligand and a neighbouring CH(2)Cl(2) molecule.
标题化合物[CuI(C₁₇H₂₁N₅)]·CH₂Cl₂包含一个具有不寻常扭曲四面体立体化学的四配位Cu(I)中心，这种情况在其他含有该三齿配体的Cu(I)配合物中也有观察到。这种扭曲可能是由于I⁻配体与相邻的CH₂Cl₂分子之间的分子间空间接触所致。
