Asano Keiji G, Bayne Charles K, Horsman Katie M, Buchanan Michelle V
Chemical Sciences Division, Oak Ridge National Laboratory, TN 37831-6365, USA.
J Forensic Sci. 2002 Jul;47(4):805-7.
This work investigates the chemical nature of fingerprints to ascertain whether differences in chemical composition or the existence of chemical markers can be used to determine personal traits, such as age, gender, and personal habits. This type of information could be useful for reducing the pool of potential suspects in criminal investigations when latent fingerprints are unsuitable for comparison by traditional methods. Fingertip residue that has been deposited onto a bead was extracted with a solvent such as chloroform. Samples were analyzed by gas chromatography/mass spectrometry (GC/MS). The chemical components identified include fatty acids, long chain fatty acid esters, cholesterol and squalene. The area ratios of ten selected components relative to squalene were calculated for a small preliminary experiment that showed a slight gender difference for three of these components. However, when the experiment was repeated with a larger, statistically designed experiment no significant differences between genders were detected for any of the component ratios. The multivariate Hotelling's T2 test that tested all ten-component ratios simultaneously also showed no gender differences at the 5% significance level.
这项研究旨在探究指纹的化学性质,以确定化学成分的差异或化学标记物的存在是否可用于确定个人特征,如年龄、性别和个人习惯。当潜在指纹不适用于传统方法进行比对时,这类信息有助于缩小刑事调查中潜在嫌疑人的范围。沉积在珠子上的指尖残留物用氯仿等溶剂进行提取。样品通过气相色谱/质谱联用仪(GC/MS)进行分析。鉴定出的化学成分包括脂肪酸、长链脂肪酸酯、胆固醇和角鲨烯。在一个小型初步实验中,计算了十种选定成分相对于角鲨烯的面积比,结果显示其中三种成分存在轻微的性别差异。然而,当用一个更大的、经过统计设计的实验重复该实验时,未检测到任何成分比例在性别之间存在显著差异。同时对所有十种成分比例进行测试的多变量霍特林T2检验在5%的显著性水平上也未显示出性别差异。