Michalski Seth, Shaler Robert, Dorman Frank L
The Pennsylvania State University, Forensic Science Program, 107 Whitmore Laboratories, University Park, PA 16802, USA.
J Forensic Sci. 2013 Jan;58 Suppl 1:S215-20. doi: 10.1111/1556-4029.12010. Epub 2012 Oct 19.
Despite advances in DNA, fingermarks remain one the best forms of evidence available. While fingermarks are routinely analyzed in terms of their patterns, it may be possible to obtain additional information in terms of their chemical composition. If successful, a chemical analysis of the constituents of a fingermark may give scientists additional information that may help in the identification of a person. The results presented herein describe the initial investigation into the analytical determination of some of these compounds, specifically the fatty acids. This study was specifically aimed at identifying possible fatty acids, which could aid in profiling or perhaps uniquely identifying an individual. Preliminary data obtained in this study suggests that this may in fact be possible, though additional research is certainly necessary. Utilizing gas chromatography-mass spectrometry, significant differences in the ratios of several fatty acid methyl esters were found when comparing individuals of varying race and gender. In addition, large intervariability and intravariability was discovered for some compounds, suggesting the possibility of being able to individualize based on chemical profile. Follow-up investigations will continue to determine whether this continues to be the case as greater numbers of individuals are sampled and more extensive control and information on the subjects is obtained.
尽管DNA技术取得了进展,但指纹仍然是现有的最佳证据形式之一。虽然指纹通常是根据其图案进行分析的,但从其化学成分方面获取更多信息或许是可行的。如果成功的话,对指纹成分进行化学分析可能会为科学家提供有助于识别个人的更多信息。本文给出的结果描述了对其中一些化合物,特别是脂肪酸进行分析测定的初步研究。这项研究的具体目标是识别可能有助于进行特征分析或甚至唯一识别个体的脂肪酸。本研究获得的初步数据表明这实际上可能是可行的,不过当然还需要更多的研究。利用气相色谱 - 质谱联用技术,在比较不同种族和性别的个体时,发现几种脂肪酸甲酯的比例存在显著差异。此外,还发现某些化合物存在较大的个体间和个体内变异性,这表明有可能根据化学特征实现个体化识别。后续调查将继续确定随着更多个体被采样以及获得关于受试者更广泛的对照和信息,情况是否依然如此。