聚[1-(三甲基硅基)-1-丙炔]作为色谱吸附剂及其在填充柱和毛细管柱中的应用前景。
Poly[1-(trimethylsilyl)-1-propine] as chromatographic adsorbent and prospects of its application in packed and capillary columns.
作者信息
Berezkin Victor G, Korolev Alexander A, Malyukova Irina V, Popova Tamara P, Shiryaeva Valeriya E, Khotimskii Valerii S
机构信息
AV Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow.
出版信息
J Chromatogr A. 2002 Jun 25;960(1-2):151-8. doi: 10.1016/s0021-9673(02)00333-3.
The application of film-forming organic polymers, which are in common use in membrane technology, as chromatographic adsorbents for packed and capillary columns has been suggested. The chromatographic characteristics of poly[1-(trimethylsilyl)-1-propine] (PTMSP) as an adsorbent were studied. The film-forming properties of PTMSP simplify manufacturing of capillary and packed gas-solid columns. It was shown that separation of C1-C4 hydrocarbon gases on the columns with PTMSP is of practical interest. In the authors' opinion, PTMSP is also promising for the separation of inorganic gases.
有人提出将膜技术中常用的成膜有机聚合物用作填充柱和毛细管柱的色谱吸附剂。研究了聚1-(三甲基甲硅烷基)-1-丙炔作为吸附剂的色谱特性。PTMSP的成膜特性简化了毛细管柱和填充气固柱的制造。结果表明，用PTMSP柱分离C1-C4烃类气体具有实际意义。作者认为，PTMSP在分离无机气体方面也很有前景。
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