在一锅反应中，通过均相钯（II）和负载型钴催化剂的连续作用，由丙炔基丙二酸酯和乙酸烯丙酯催化不对称合成环戊烯酮。
Catalytic asymmetric synthesis of cyclopentenones from propargyl malonates and allylic acetate by successive action of homogeneous palladium(II) and cobalt on charcoal catalysts in a one-pot reaction.
作者信息
Son S U, Park K H, Seo H, Chung Y K, Lee S G
机构信息
School of Chemistry and Center for Molecular Catalysis, Seoul National University, Seoul 151-747, Korea.
出版信息
Chem Commun (Camb). 2001 Dec 7(23):2440-1.
PMID:12240004
Abstract
The tandem action of a homogeneous chiral Pd(II) catalyst and a heterogeneous Co/C catalyst leads to a two-step one-pot highly enantioselective Pauson-Khand-type reaction.
摘要
均相手性钯（II）催化剂和非均相钴/碳催化剂的协同作用导致了两步一锅法的高对映选择性Pauson-Khand型反应。
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