Kovtyukhova Nina I, Mallouk Thomas E
Department of Chemistry, The Pennsylvania State University, University Park 16802, USA.
Chemistry. 2002 Oct 4;8(19):4354-63. doi: 10.1002/1521-3765(20021004)8:19<4354::AID-CHEM4354>3.0.CO;2-1.
The concept of assembling electronic circuits from metal nanowires is discussed. These nanowires are synthesised electrochemically by using porous membranes as templates. High aspect ratio wires, which range from 15 to 350 nm in diameter and contain "stripes" of different metals, semiconductors, colloid/polymer multilayers, and self-assembling monolayers have been made by this technique. By using the distinct surface chemistry of different stripes, the nanowires can be selectively derivatized and positioned on patterned surfaces. This allows the current-voltage properties of single and crossed nanowire devices to be measured. Nanowire conductors, rectifiers, switches, and photoconductors have been characterized. Techniques are still being developed for assembling sublithographic scale nanowires into cross-point arrays for memory and logic applications.
本文讨论了利用金属纳米线组装电子电路的概念。这些纳米线是通过使用多孔膜作为模板,采用电化学方法合成的。利用该技术已制造出高纵横比的纳米线,其直径范围为15至350纳米,包含不同金属、半导体、胶体/聚合物多层膜和自组装单分子层的“条纹”。通过利用不同条纹独特的表面化学性质,纳米线可以被选择性地衍生化并定位在图案化表面上。这使得能够测量单根和交叉纳米线器件的电流-电压特性。纳米线导体、整流器、开关和光电导体已得到表征。目前仍在开发将亚光刻尺度的纳米线组装成用于存储器和逻辑应用的交叉点阵列的技术。