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1

Cycloaddition of cyclohexa-2,4-dienones with electron deficient 2 pi partners: a novel and stereoselective route to functionalized bicyclo[2.2.2]octenones.环己-2,4-二烯酮与缺电子2π反应物的环加成反应：一条合成官能化双环[2.2.2]辛烯酮的新颖立体选择性路线。

Chem Commun (Camb). 2002 Sep 21(18):2050-1. doi: 10.1039/b205475m.

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Cycloaddition between electron-deficient pi-systems, photochemical and radical-induced reactions: a novel, general, and stereoselective route to polyfunctionalized bridged bicyclo[2.2.2]octanes, bicyclo[3.3.0]octanes, bicyclo[4.2.0]octanes, and tricyclo[4.3.1.0(3,7)]decanes.缺电子π体系之间的环加成反应、光化学反应和自由基引发反应：一种合成多官能化桥连双环[2.2.2]辛烷、双环[3.3.0]辛烷、双环[4.2.0]辛烷和三环[4.3.1.0(3,7)]癸烷的新颖、通用且立体选择性的途径。

J Org Chem. 2006 Apr 14;71(8):3014-25. doi: 10.1021/jo052544v.

3

A novel and efficient synthesis of bicyclo[2.2.2]octenones and sigmatropic shifts in ground and excited states: stereoselective route to cis-decalins and diquinane frameworks.双环[2.2.2]辛烯酮的一种新颖高效合成方法以及基态和激发态中的[3,3] - 迁移：通向顺式十氢化萘和二喹烷骨架的立体选择性途径。

J Org Chem. 2005 Feb 4;70(3):973-81. doi: 10.1021/jo048320e.

4

Intermolecular Diels-Alder reactions of brominated masked o-benzoquinones with electron-deficient dienophiles. A detour method to synthesize bicyclo[2.2.2]octenones from 2-methoxyphenols.溴化掩蔽邻苯醌与缺电子亲双烯体的分子间狄尔斯-阿尔德反应。一种从2-甲氧基苯酚合成双环[2.2.2]辛烯酮的迂回方法。

J Org Chem. 2002 Sep 6;67(18):6493-502. doi: 10.1021/jo020171h.

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Cycloaddition of cyclohexa-2,4-dienones, ring-closing metathesis, and photochemical reactions: a common stereoselective approach to duprezianane, polyquinane and sterpurane frameworks.环己-2,4-二烯酮的环加成反应、关环复分解反应及光化学反应：一种构建杜普雷扎烷、多喹烷和斯德普烷骨架的通用立体选择性方法。

J Org Chem. 2007 Mar 16;72(6):2058-67. doi: 10.1021/jo062416m. Epub 2007 Feb 21.

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Molecular complexity from aromatics: a novel, stereoselective route to tricyclo[5.2.2.0(1,5)]undecenones, tricyclo[6.2.2.0(1,6)]dodecenones, and [n.3.3]propellanes.来自芳烃的分子复杂性：一种合成三环[5.2.2.0(1,5)]十一碳烯酮、三环[6.2.2.0(1,6)]十二碳烯酮和[n.3.3]螺桨烷的新颖立体选择性路线。

J Org Chem. 2007 Dec 21;72(26):10155-65. doi: 10.1021/jo702168s. Epub 2007 Nov 30.

7

Catalytic Friedel-Crafts Alkylative Desymmetrization of Cyclohexa-2,5-dienones: Access to Linear and Bridged Polycyclic Pyrroles and 3-Arylpyrroles.

Org Lett. 2022 Jul 19. doi: 10.1021/acs.orglett.2c02135.

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Diels-Alder cycloaddition and ring-closing metathesis: a versatile, stereoselective, and general route to embellished bridged bicyclic systems, carbocyclic framework of secoatisanes, and homologues.Diels-Alder 环加成和环 closing 复分解反应：一种通用、立体选择性的方法，用于构建修饰的桥环双环系统、secocis-atisanes 的碳环骨架和同系物。

J Org Chem. 2009 Aug 21;74(16):6092-104. doi: 10.1021/jo901279g.

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Cycloaddition of Spiroepoxycyclohexa-2,4-dienones, Radical Cyclization and 1,3-Acyl Shift in Excited State: Aromatics to Sterpuren-4-one.螺环氧环己二烯酮的环加成、激发态下的自由基环化和 1,3-酰基迁移：芳烃到甾醇-4-酮。

J Org Chem. 2017 Jun 16;82(12):6268-6278. doi: 10.1021/acs.joc.7b00867. Epub 2017 Jun 7.

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Efficient synthesis and subsequent transformations of phenylsulfanylbicyclo[2.2.2]octenones and phenylselenylbicyclo[2.2.2]octenones.苯硫基双环[2.2.2]辛烯酮和苯硒基双环[2.2.2]辛烯酮的高效合成及后续转化

J Org Chem. 2009 Feb 20;74(4):1632-9. doi: 10.1021/jo802295p.

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环己-2,4-二烯酮与缺电子2π反应物的环加成反应：一条合成官能化双环[2.2.2]辛烯酮的新颖立体选择性路线。

Cycloaddition of cyclohexa-2,4-dienones with electron deficient 2 pi partners: a novel and stereoselective route to functionalized bicyclo[2.2.2]octenones.

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