Wu Chuan-De, Lu Can-Zhong, Zhuang Hong-Hui, Huang Jin-Shun
The State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, the Chinese Academy of Sciences, Fuzhou, Fujian 350002, P.R. China.
Inorg Chem. 2002 Nov 4;41(22):5636-7. doi: 10.1021/ic025668o.
The one-dimensional polymer, Cu(2)(C(8)H(6)N(2))(2)(C(7)H(6)N(2))[Mo(8)O(26)] (1), which consists of beta-Mo(8)O(26)(-) anions linked by quinoxaline and its oxidized product benzimidazole ligands coordinated to binuclear copper(I) fragments, provides the first demonstration that the isolated copper(I) complex under hydrothermal conditions "captures" the reduction product of original starting organonitrogen ligand to form a copper(I)-beta-octamolybdate complex.
一维聚合物[Cu₂(C₈H₆N₂)₂(C₇H₆N₂)]₂[Mo₈O₂₆] (1)，由通过喹喔啉连接的β-[Mo₈O₂₆]⁴⁻阴离子以及与双核铜(I)片段配位的其氧化产物苯并咪唑配体组成，首次证明了在水热条件下分离出的铜(I)配合物“捕获”了原始起始有机氮配体的还原产物，形成了铜(I)-β-八钼酸盐配合物。
