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2,2,3,3'-四苯基-7,7'-联喹喔啉

2,2,3,3'-Tetra-phenyl-7,7'-biquinoxaline.

作者信息

Dueno Eric E, Gibson Ricky Joseph Paul, Salvatore Ralph Nicholas, Pike Robert D, Zambrano Cesar H

出版信息

Acta Crystallogr Sect E Struct Rep Online. 2007 Dec 6;64(Pt 1):o110-1. doi: 10.1107/S1600536807033521.

DOI:10.1107/S1600536807033521
PMID:21200675
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC2915182/
Abstract

In the crystal structure of the title compound, C(40)H(26)N(4), mol-ecules reside on crystallographic centers of inversion and are linked via C-H⋯N inter-actions about inversion centers into one-dimensional chains: longer C-H⋯π(arene) inter-actions complete the inter-molecular inter-actions.

摘要

在标题化合物C(40)H(26)N(4)的晶体结构中，分子位于晶体学倒转中心上，并通过围绕倒转中心的C-H⋯N相互作用连接成一维链：较长的C-H⋯π(芳烃)相互作用完善了分子间相互作用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f23/2915182/ff269bd3e637/e-64-0o110-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f23/2915182/f2764696ac5e/e-64-0o110-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f23/2915182/ff269bd3e637/e-64-0o110-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f23/2915182/f2764696ac5e/e-64-0o110-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9f23/2915182/ff269bd3e637/e-64-0o110-fig2.jpg

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本文引用的文献

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Simultaneous solid-phase synthesis of quinoxalinone and benzimidazole scaffold libraries.喹喔啉酮和苯并咪唑支架文库的同步固相合成。
J Comb Chem. 2006 Nov-Dec;8(6):841-7. doi: 10.1021/cc060074s.
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Diverse 2-carboxamide-3-amino-substituted quinoxalines: synthesis and reactivity investigation for library generation.多样的2-甲酰胺基-3-氨基取代喹喔啉：用于文库生成的合成及反应性研究
J Comb Chem. 2006 Sep-Oct;8(5):774-9. doi: 10.1021/cc060058v.
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Hybrid coordination polymer constructed from beta-octamolybdates linked by quinoxaline and its oxidized product benzimidazole coordinated to binuclear copper(I) fragments.
由喹喔啉连接的β-八钼酸盐及其氧化产物苯并咪唑与双核铜（I）片段配位构建的杂化配位聚合物。
Inorg Chem. 2002 Nov 4;41(22):5636-7. doi: 10.1021/ic025668o.
4
New software for searching the Cambridge Structural Database and visualizing crystal structures.用于搜索剑桥结构数据库和可视化晶体结构的新软件。
Acta Crystallogr B. 2002 Jun;58(Pt 3 Pt 1):389-97. doi: 10.1107/s0108768102003324. Epub 2002 May 29.
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Novel copper(I) halide polymers: structures of Cu(2)Br(2)(2,3-dimethylquinoxaline) and (2,3-Di(bromomethyl)quinoxalinium)CuBr(2). The continuing saga of copper(II) bromide reactivity with organoamines.新型卤化亚铜聚合物：Cu(2)Br(2)(2,3 - 二甲基喹喔啉)和(2,3 - 二(溴甲基)喹喔啉鎓)CuBr(2)的结构。溴化铜与有机胺反应的持续故事。
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6
Altering the Balance between Ligand-Based Radical Anion Formation and Dechelation in Electrochemically Reduced Binuclear Copper(I) Complexes: A Resonance Raman Spectroelectrochemical Study.电化学还原双核铜（I）配合物中基于配体的自由基阴离子形成与脱螯合之间平衡的改变：共振拉曼光谱电化学研究
Inorg Chem. 1998 Aug 24;37(17):4452-4459. doi: 10.1021/ic9715052.
7
Quinoxaline antibiotics enhance peptide nucleic acid binding to double-stranded DNA.喹喔啉类抗生素增强肽核酸与双链DNA的结合。
Biochemistry. 2000 Aug 8;39(31):9502-7. doi: 10.1021/bi000254x.