• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

八(二丁基铵)十钼酸(VI)

Octa-kis(di-butyl-ammonium) deca-molybdate(VI).

作者信息

Gueye Papa Aly, Yaffa Lamine, Seye Dame, Ndoye Daouda, Traoré Bocar, Sidibé Mamadou, Diop Cheikh Abdoul Khadir, Shova Sergiu

机构信息

Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop de Dakar, Senegal.

Département Physique Chimie, UFR Sciences et Technologies, Université Ibra Der Thiam de Thiès, Senegal.

出版信息

IUCrdata. 2024 May 31;9(Pt 5):x240463. doi: 10.1107/S2414314624004632. eCollection 2024 May.

DOI:10.1107/S2414314624004632
PMID:38846552
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11151287/
Abstract

In the title salt, (CHN)[MoO], the [MoO] polyanion is located about an inversion centre and can be considered as a -type octa-molybdate anion to which two additional MoO tetra-hedra are linked common corners. The [MoO] polyanions are packed in rows extending parallel to [001] and are connected to the di-butyl-ammonium counter-cations through N-H⋯O hydrogen-bonding inter-actions.

摘要

在标题盐(CHN)[MoO]中,[MoO]多阴离子位于一个反演中心周围,可被视为一种α型八钼酸根阴离子,有两个额外的MoO四面体通过公共角与之相连。[MoO]多阴离子平行于[001]方向排成行堆积,并通过N-H⋯O氢键相互作用与二丁基铵抗衡阳离子相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdb1/11151287/cad1a50bf6d9/x-09-x240463-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdb1/11151287/b10b7b0e5ee4/x-09-x240463-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdb1/11151287/f323d897730a/x-09-x240463-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdb1/11151287/c9c8cc6e2183/x-09-x240463-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdb1/11151287/cad1a50bf6d9/x-09-x240463-fig4.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdb1/11151287/b10b7b0e5ee4/x-09-x240463-fig1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdb1/11151287/f323d897730a/x-09-x240463-fig2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdb1/11151287/c9c8cc6e2183/x-09-x240463-fig3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdb1/11151287/cad1a50bf6d9/x-09-x240463-fig4.jpg

相似文献

1
Octa-kis(di-butyl-ammonium) deca-molybdate(VI).八(二丁基铵)十钼酸(VI)
IUCrdata. 2024 May 31;9(Pt 5):x240463. doi: 10.1107/S2414314624004632. eCollection 2024 May.
2
Crystal structure of octa-kis-(N,N-di-methyl-formamide-κO)europium(III) tetra-cosa-μ2-oxido-dodeca-oxido-μ12-phosphato-dodeca-molybdate(VI).八-双-(N,N-二甲基甲酰胺-κO)铕(III)二十四-μ2-氧代-十二氧代-μ12-磷酸根-十二钼酸根(VI)的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 Mar 4;72(Pt 4):448-51. doi: 10.1107/S2056989016003546. eCollection 2016 Apr 1.
3
Penta-ammonium hepta-sodium bis-[penta-kis(μ(2)-oxido)deca-oxido-bis-(μ(5)-phosphato)penta-molybdenum(VI)] henicosa-hydrate.七水合双[五(μ(2)-氧化)十氧化双(μ(5)-磷酸根)五钼酸(VI)]五铵七钠
Acta Crystallogr Sect E Struct Rep Online. 2010 Feb 20;66(Pt 3):i20-i21. doi: 10.1107/S160053681000601X.
4
Redetermination of the crystal structure of 3,5-di-methyl-pyrazolium β-octa-molybdate tetra-hydrate.3,5-二甲基吡唑鎓β-八钼酸四水合物晶体结构的重新测定
Acta Crystallogr E Crystallogr Commun. 2015 Dec 6;71(Pt 12):m244-5. doi: 10.1107/S2056989015022823. eCollection 2015 Dec 1.
5
Tetra-ammonium bis-(metforminium) di-μ-oxido-tetra-μ-oxido-tetra-deca-μ-oxido-octa-oxidodeca-vanadium(V) hexa-hydrate.六水合双(二甲双胍)四铵二-μ-氧代-四-μ-氧代-十四-μ-氧代-八氧化十钒(V)
IUCrdata. 2021 Jun 25;6(Pt 6):x210634. doi: 10.1107/S2414314621006349. eCollection 2021 Jun.
6
Two di-alkyl-ammonium salts of 2-amino-4-nitro-benzoic acid: crystal structures and Hirshfeld surface analysis.2-氨基-4-硝基苯甲酸的两种二烷基铵盐:晶体结构与 Hirshfeld 表面分析
Acta Crystallogr E Crystallogr Commun. 2016 Nov 1;72(Pt 12):1691-1699. doi: 10.1107/S2056989016017266. eCollection 2016 Dec 1.
7
Ethyl-enedi-ammonium sodium tetra-kis-[bis-(ethyl-enedi-amine-κ(2) N,N')(oxalato-κ(2) O (1),O (2))cobalt(III)] [penta-hydrogen di(phosphato-octa-deca-tungstate)] tetra-deca-hydrate.四水合[五氢二(磷酸十八钨酸盐)]四水合乙二铵钠四[双(乙二胺-κ(2) N,N')(草酸根-κ(2) O(1),O(2))钴(III)]
Acta Crystallogr Sect E Struct Rep Online. 2013 Oct 16;69(Pt 11):m605-6. doi: 10.1107/S160053681302583X.
8
Bis-[4,4'-(propane-1,3-di-yl)-dipiperidin-ium] β-octa-molybdate(VI).双-[4,4'-(丙烷-1,3-二亚基)-二哌啶鎓]β-八钼酸(VI)
Acta Crystallogr Sect E Struct Rep Online. 2010 Apr 17;66(Pt 5):m533-4. doi: 10.1107/S1600536810013632.
9
Crystal structure of hexa-kis-(di-methyl-formamide-κO)manganese(II) deca-kis-(di-methyl-formamide)-1κ(5) O,2κ(5) O-[μ-octa-deca-tungstodiphosphato(V)-κO:κO']dimanganate(II) di-methyl-formamide disolvate.六-双(二甲基甲酰胺-κO)锰(II)十-双(二甲基甲酰胺)-1κ(5)O,2κ(5)O-[μ-十八钨二磷酸根合(V)-κO:κO']二锰酸(II)二甲基甲酰胺二溶剂合物的晶体结构
Acta Crystallogr E Crystallogr Commun. 2016 May 20;72(Pt 6):841-4. doi: 10.1107/S2056989016007842. eCollection 2016 Jun 1.
10
Crystal structure of bis-(diiso-propyl-ammonium) molybdate.二(二异丙基铵)钼酸盐的晶体结构
Acta Crystallogr E Crystallogr Commun. 2018 Oct 31;74(Pt 11):1682-1685. doi: 10.1107/S2056989018014755. eCollection 2018 Nov 1.

本文引用的文献

1
Naphthylimido-substituted hexamolybdate: preparation, crystal structures, solvent effects, and optical properties of three polymorphs.
Inorg Chem. 2007 Jun 11;46(12):4960-7. doi: 10.1021/ic070064b. Epub 2007 May 10.
2
Hydrothermal synthesis and structure of a new helical chain constructed from only molybdenum-oxide building blocks.由仅含氧化钼结构单元构建的新型螺旋链的水热合成与结构
Inorg Chem. 2003 Nov 17;42(23):7342-4. doi: 10.1021/ic034331z.
3
Hybrid coordination polymer constructed from beta-octamolybdates linked by quinoxaline and its oxidized product benzimidazole coordinated to binuclear copper(I) fragments.由喹喔啉连接的β-八钼酸盐及其氧化产物苯并咪唑与双核铜(I)片段配位构建的杂化配位聚合物。
Inorg Chem. 2002 Nov 4;41(22):5636-7. doi: 10.1021/ic025668o.
4
"Molecular symmetry breakers" generating metal-oxide-based nanoobject fragments as synthons for complex structures: [[Mo(128)Eu(4)O(388)H(10)(H(2)O)(81)](2)](20-), a giant-cluster dimer.生成基于金属氧化物的纳米物体片段作为复杂结构合成子的“分子对称性破坏者”:[[Mo(128)Eu(4)O(388)H(10)(H₂O)(81)](2)](20-),一种巨型簇二聚体。
Angew Chem Int Ed Engl. 2002 Aug 2;41(15):2805-8. doi: 10.1002/1521-3773(20020802)41:15<2805::AID-ANIE2805>3.0.CO;2-E.