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八(二丁基铵)十钼酸(VI)

Octa-kis(di-butyl-ammonium) deca-molybdate(VI).

作者信息

Gueye Papa Aly, Yaffa Lamine, Seye Dame, Ndoye Daouda, Traoré Bocar, Sidibé Mamadou, Diop Cheikh Abdoul Khadir, Shova Sergiu

机构信息

Laboratoire de Chimie Minérale et Analytique (LACHIMIA), Département de Chimie, Faculté des Sciences et Techniques, Université Cheikh Anta Diop de Dakar, Senegal.

Département Physique Chimie, UFR Sciences et Technologies, Université Ibra Der Thiam de Thiès, Senegal.

出版信息

IUCrdata. 2024 May 31;9(Pt 5):x240463. doi: 10.1107/S2414314624004632. eCollection 2024 May.

Abstract

In the title salt, (CHN)[MoO], the [MoO] polyanion is located about an inversion centre and can be considered as a -type octa-molybdate anion to which two additional MoO tetra-hedra are linked common corners. The [MoO] polyanions are packed in rows extending parallel to [001] and are connected to the di-butyl-ammonium counter-cations through N-H⋯O hydrogen-bonding inter-actions.

摘要

在标题盐(CHN)[MoO]中,[MoO]多阴离子位于一个反演中心周围,可被视为一种α型八钼酸根阴离子,有两个额外的MoO四面体通过公共角与之相连。[MoO]多阴离子平行于[001]方向排成行堆积,并通过N-H⋯O氢键相互作用与二丁基铵抗衡阳离子相连。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/cdb1/11151287/b10b7b0e5ee4/x-09-x240463-fig1.jpg

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