Linear alignment of four sulfur atoms in bis[(8-phenylthio)naphthyl] disulfide: contribution of linear S4 hypervalent four-centre six-electron bond to the structure.
作者信息
Nakanishi Warô, Hayashi Satoko, Arai Takamitsu
机构信息
Department of Material Science and Chemistry, Faculty of Systems Engineering, Wakayama University, 930 Sakaedani, Wakayama 640-8510, Japan.
出版信息
Chem Commun (Camb). 2002 Oct 21(20):2416-7. doi: 10.1039/b206137f.
DOI:10.1039/b206137f
PMID:12430468
Abstract
The four sulfur atoms in bis[8-(phenylthio)naphthyl]-1,1'-disulfide are demonstrated to align linearly by the X-ray crystallographic analysis, where the linear S4 alignment is stabilized by the four-centre six-electron interaction.
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