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用氧同位素δ值制作一个可靠的测量尺度。

Making an honest measurement scale out of the oxygen isotope delta-values.

作者信息

Gat Joel R, DeBievre Paul

机构信息

Department of Environmental Sciences and Energy Research, The Weizmann Institute of Science, Rehovot, Israel.

出版信息

Rapid Commun Mass Spectrom. 2002;16(23):2205-7. doi: 10.1002/rcm.857.

Abstract

The differential measurement of the abundance of oxygen isotopes based on reference materials, such as VSMOW for the case of water, was used because the precision of the absolute mass-spectrometric determination of the abundance fell short of the differences to be measured. Since then these measurements have been much improved, so that a calibration scheme of the oxygen isotope abundance in water, carbonates, silica, phosphates, sulfates, nitrates and organic materials is suggested, based on an accredited primary standard of oxygen in air and using standard fluorination and O(2) to CO(2) conversion techniques.

摘要

基于参考物质(如水的VSMOW)对氧同位素丰度进行差异测量,这是因为绝对质谱法测定丰度的精度不足以测量出所需的差异。从那时起,这些测量有了很大改进,因此,基于空气中经认可的氧初级标准,并使用标准氟化和O(2)到CO(2)的转换技术,提出了一种水、碳酸盐、二氧化硅、磷酸盐、硫酸盐、硝酸盐和有机材料中氧同位素丰度的校准方案。

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