Frieden B R, Plastino A, Plastino A R, Soffer B H
University of Arizona, Tucson, Arizona 85721, USA.
Phys Rev E Stat Nonlin Soft Matter Phys. 2002 Oct;66(4 Pt 2):046128. doi: 10.1103/PhysRevE.66.046128. Epub 2002 Oct 22.
It is known that equilibrium thermodynamics can be deduced from a constrained Fisher information extemizing process. We show here that, more generally, both nonequilibrium and equilibrium thermodynamics can be obtained from such a Fisher treatment. Equilibrium thermodynamics corresponds to the ground-state solution, and nonequilibrium thermodynamics corresponds to excited-state solutions, of a Schrödinger wave equation (SWE). That equation appears as an output of the constrained variational process that extremizes Fisher information. Both equilibrium and nonequilibrium situations can thereby be tackled by one formalism that clearly exhibits the fact that thermodynamics and quantum mechanics can both be expressed in terms of a formal SWE, out of a common informational basis. As an application, we discuss viscosity in dilute gases.
众所周知,平衡态热力学可以从一个受约束的使费希尔信息最大化的过程推导出来。我们在此表明,更一般地,非平衡态和平衡态热力学都可以通过这样一种费希尔处理得到。平衡态热力学对应于薛定谔波动方程(SWE)的基态解,而非平衡态热力学对应于该方程的激发态解。该方程作为使费希尔信息最大化的受约束变分过程的一个输出而出现。因此,平衡态和非平衡态情况都可以通过一种形式体系来处理,这种形式体系清楚地展示了热力学和量子力学都可以从一个共同的信息基础出发,用一个形式上的薛定谔波动方程来表达这一事实。作为一个应用,我们讨论稀薄气体中的黏性。