Moon B H, Seo G T, Lee T S, Kim S S, Yoon C H
Department of Environmental Engineering, Changwon National University, Changwon, Korea.
Water Sci Technol. 2003;47(1):65-70.
Most seafood wastewater has been treated by the activated sludge process. Due to changes in salt concentration, pollutant loadings and raw materials, the process is not operated satisfactorily to meet effluent regulation. Most problems faced at present are solid liquid separation. In this study, effects of salt concentration on floc characteristics and pollutants removal efficiencies were investigated in treatment of seafood wastewater by SBR. For analyzing fractal dimension of flocs, the small angle laser light scattering (SALLS) method was applied using a Diffraction Particle Sizer (Malvern Instruments). Organic removal efficiencies (in terms of COD(Mn)) decreased with increasing salt concentration, but eventually reached a steady state. Fractal dimension and floc size also showed similar trends with changing salt concentration. The main reasons to reduced pollutant removal efficiencies were deteriorated biological activity and settling properties. The biological activity was affected faster than the floc characteristics by increasing salt concentration. The deteriorated settling properties were explained by decreased size and fractal dimension of floc due to increasing salt concentration. The settling properties of floc such as sludge volume index (SVI) and zone settling velocity (ZSV) were related to size and fractal dimension of floc. The fractal dimension of floc was better related to the settling properties than the size of floc.
大多数海产品废水已通过活性污泥法进行处理。由于盐浓度、污染物负荷和原材料的变化,该工艺无法令人满意地运行以达到排放标准。目前面临的大多数问题是固液分离。在本研究中,通过SBR处理海产品废水时,研究了盐浓度对絮体特性和污染物去除效率的影响。为了分析絮体的分形维数,使用衍射粒度分析仪(马尔文仪器公司)采用小角激光光散射(SALLS)法。有机物去除效率(以COD(Mn)计)随着盐浓度的增加而降低,但最终达到稳定状态。分形维数和絮体尺寸也随盐浓度的变化呈现相似趋势。污染物去除效率降低的主要原因是生物活性和沉降性能恶化。盐浓度增加对生物活性的影响比对絮体特性的影响更快。沉降性能恶化的原因是盐浓度增加导致絮体尺寸和分形维数减小。絮体的沉降性能,如污泥体积指数(SVI)和区域沉降速度(ZSV),与絮体的尺寸和分形维数有关。絮体的分形维数比分形尺寸与沉降性能的相关性更好。