[枫香脂的化学成分——路路通]

[Chemical composition of fructus Liquidambaris--lulutong].

作者信息

Li Chun, Sun Yu-ru, Sun You-fu

机构信息

Institute of Chinese Materia Medica, China Academy of Traditional Chinese Medicine, Beijing 100700, China.

出版信息

Yao Xue Xue Bao. 2002 Apr;37(4):263-6.

PMID:12579820

Abstract

AIM

To study the chemical composition in the fruits of Liquidambar formana Hance.

METHODS

Various column chromatographic techniques were used to separate and purify the constituents. Their physical and chemical properties and spectral data were measured for structural elucidation.

RESULTS

Eleven compounds were isolated and identified as beta-sitosterol (1), 3-oxo-11 alpha, 12 alpha-epoxyleanan-28, 13 beta-olide (2), 3-oxo-12 alpha-hydroxy-oleanan-28, 13 beta-olide (3), 3 alpha-acetyloxy-25-hydroxyolean-12-en-28-oic acid (4), oleanolic acid (5), ursolic acid (6), daucosterol (7), betulonic acid (8), gallic acid (9), nonacosane (10) and n-triacontanoic acid (11).

CONCLUSION

Among the isolated constituents, compound 4 is new compound, compound 3 is firstly isolated from the natural product and compound 5, 6, 7, 9, 10 and 11 are isolated from LuLuTong for the first time.

摘要

目的

研究枫香树果实中的化学成分。

方法

采用多种柱色谱技术分离和纯化各成分。测定其物理化学性质和光谱数据以进行结构鉴定。

结果

分离鉴定出11种化合物，分别为β-谷甾醇（1）、3-氧代-11α，12α-环氧羽扇豆-28，13β-内酯（2）、3-氧代-12α-羟基齐墩果烷-28，13β-内酯（3）、3α-乙酰氧基-25-羟基齐墩果-12-烯-28-酸（4）、齐墩果酸（5）、熊果酸（6）、胡萝卜苷（7）、桦木酸（8）、没食子酸（9）、二十九烷（10）和正三十烷酸（11）。