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Sc3N@C68: folded pentalene coordination in an endohedral fullerene that does not obey the isolated pentagon rule.

作者信息

Olmstead Marilyn M, Lee Hon Man, Duchamp James C, Stevenson Steven, Marciu Daniela, Dorn Harry C, Balch Alan L

机构信息

Department of Chemistry, University of California, Davis 95616, USA.

出版信息

Angew Chem Int Ed Engl. 2003 Feb 24;42(8):900-3. doi: 10.1002/anie.200390237.

DOI:10.1002/anie.200390237
PMID:12596171
Abstract
摘要

相似文献

1
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2
Diels-Alder reaction on free C₆₈ fullerene and endohedral Sc₃N@C₆₈ fullerene violating the isolated pentagon rule: importance of pentagon adjacency.游离C₆₈富勒烯和内包Sc₃N@C₆₈富勒烯上违反孤立五边形规则的狄尔斯-阿尔德反应:五边形邻接的重要性
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3
A facile route to the non-IPR fullerene Sc3N@C68: synthesis, spectroscopic characterization, and density functional theory computations (IPR=isolated pentagon rule).一种合成非孤立五边形规则富勒烯Sc3N@C68的简便方法:合成、光谱表征及密度泛函理论计算(IPR=孤立五边形规则)
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4
13C NMR pattern of Sc3N@C68. Structural assignment of the first fullerene with adjacent pentagons.Sc3N@C68的13C核磁共振图谱。首个具有相邻五边形的富勒烯的结构归属。
J Phys Chem A. 2005 Aug 18;109(32):7068-72. doi: 10.1021/jp052062n.
5
Bingel-Hirsch addition on non-isolated-pentagon-rule Gd3N@C2n (2n = 82 and 84) metallofullerenes: products under kinetic control.宾格尔-赫希加成反应在非孤立五边形规则 Gd3N@C2n(2n = 82 和 84)金属富勒烯中的应用:动力学控制下的产物。
J Org Chem. 2013 Oct 4;78(19):9986-90. doi: 10.1021/jo4014832. Epub 2013 Sep 16.
6
Charged states of Sc3N@C68: an in situ spectroelectrochemical study of the radical cation and radical anion of a non-IPR fullerene.Sc3N@C68的电荷态:非孤立五元环富勒烯自由基阳离子和自由基阴离子的原位光谱电化学研究
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Bingel-Hirsch addition on endohedral metallofullerenes: kinetic versus thermodynamic control.笼型金属富勒烯 Bingel-Hirsch 加成:动力学控制与热力学控制。
Chemistry. 2013 Apr 15;19(16):5061-9. doi: 10.1002/chem.201203522. Epub 2013 Feb 19.
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The maximum pentagon separation rule provides a guideline for the structures of endohedral metallofullerenes.最大五角形分离规则为金属富勒烯笼内化合物的结构提供了指导。
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Large metal ions in a relatively small fullerene cage: the structure of Gd3N@C2(22010)-C78 departs from the isolated pentagon rule.相对较小的富勒烯笼中的大金属离子:Gd3N@C2(22010)-C78的结构偏离了孤立五边形规则。
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The spin state of a charged non-IPR fullerene: the stable radical cation of Sc3N@C68.
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