Barlow Anna J, Lorimer Stephen D, Morgan Ed R, Weavers Rex T
Department of Chemistry, University of Otago, PO Box 56, Dunedin, New Zealand.
Phytochemistry. 2003 May;63(1):25-9. doi: 10.1016/s0031-9422(02)00725-2.
The incorporation of [1-13C] labelled glucose into hodgsonox, a sesquiterpene epoxide with a unique, doubly allylic ether functionality has been studied in axenic cultures of the liverwort Lepidolaena hodgsoniae. Quantitative 13C NMR spectroscopic analysis showed that the isoprene units are derived exclusively from the methylerythritol phosphate pathway.
在叶苔类植物霍氏鳞叶苔(Lepidolaena hodgsoniae)的无菌培养物中,研究了[1-¹³C]标记的葡萄糖掺入霍奇松醇(hodgsonox)的情况,霍奇松醇是一种具有独特双烯丙基醚官能团的倍半萜环氧化物。定量¹³C NMR光谱分析表明,异戊二烯单元仅来源于甲基赤藓糖醇磷酸途径。