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[气相色谱-质谱联用测定孜然挥发油的化学成分]

[Determination of chemical components of volatile oil from Cuminum cyminum L. by gas chromatography-mass spectrometry].

作者信息

Yan Jian-hui, Tang Ke-wen, Zhong Ming, Deng Ning-hua

机构信息

Department of Chemistry and Chemical Engineering, Yueyang Normal University, Yueyang 414000, China.

出版信息

Se Pu. 2002 Nov;20(6):569-72.

Abstract

Volatile oil was extracted from Cuminum cyminum L. by using steam distillation. More than sixty peaks were separated and 49 compounds were identified by gas chromatography-mass spectrometry (GC-MS). The relative amounts of the components were determined by area normalization method. Among the 49 compounds identified, there were 16 hydrocarbons and 32 oxygenated compounds. The main compnents were cuminal and safranal (accounting for 32.26% and 24.46% respectively in the components identified). The other nine compounds with contents all over 1%, were monterpenes, sesquiterpenes, aromatic aldehydes and aromatic oxides etc. The other components with relatively small amounts were chiefly terpenes, terpenols, terpenals, terpenones, terpene esters and aromatic compounds. It is good to separate polar and apolar components in the volatile oil from Cuminum cyminum L. on the GC capillary column of moderate polarity.

摘要

采用水蒸气蒸馏法从孜然中提取挥发油。经气相色谱 - 质谱联用(GC - MS)分离出60多个峰,并鉴定出49种化合物。采用面积归一化法测定各成分的相对含量。在鉴定出的49种化合物中,有16种烃类和32种含氧化合物。主要成分是枯茗醛和藏红花醛(在鉴定出的成分中分别占32.26%和24.46%)。其他9种含量均超过1%的化合物为单萜、倍半萜、芳香醛和芳香氧化物等。其他含量相对较少的成分主要是萜类、萜醇、萜醛、萜酮、萜酯和芳香族化合物。在中等极性的GC毛细管柱上分离孜然挥发油中的极性和非极性成分效果良好。

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