Durandetti Muriel, Meignein Clotilde, Périchon Jacques
Laboratoire d'Electrochimie, Catalyse et Synthèse Organique, UMR 7582 CNRS, 2 rue Henri-Dunant, 94320 Thiais, France.
J Org Chem. 2003 Apr 18;68(8):3121-4. doi: 10.1021/jo026782r.
Homoallylic alcohols were synthesized from aldehydes or ketones and allylic acetates, using an electrochemical process catalyzed by iron complexes. We first studied the reactivity of allyl acetate, using N,N-dimethylformamide (DMF) or acetonitrile (AN) as solvent, FeBr(2) as catalyst, and Fe as the sacrificial anode. Then we tested the regioreactivity of crotyl acetate and other allylic derivatives.
通过铁配合物催化的电化学过程，由醛或酮与烯丙基乙酸酯合成了高烯丙醇。我们首先以N，N-二甲基甲酰胺（DMF）或乙腈（AN）为溶剂，FeBr₂为催化剂，Fe为牺牲阳极，研究了乙酸烯丙酯的反应活性。然后我们测试了乙酸巴豆酯和其他烯丙基衍生物的区域反应性。
