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Covalent crosslinking of 1-D photonic crystals of microporous Si by hydrosilylation and ring-opening metathesis polymerization.

作者信息

Yoon Myeong Sik, Ahn Kyo Han, Cheung Ronnie W, Sohn Honglae, Link Jamie R, Cunin Frédérique, Sailor Michael J

机构信息

Department of Chemistry and Center for Integrated Molecular Systems, Division of Molecular and Life Science, Pohang University of Science & Technology, San 31 Hyoja-dong, Pohang 790-784, Republic of Korea.

出版信息

Chem Commun (Camb). 2003 Mar 21(6):680-1. doi: 10.1039/b300937h.

Abstract

Free-standing porous Si multilayer dielectric mirrors, prepared by electrochemical etching of crystalline Si, are treated with a ruthenium ring-opening metathesis polymerization (ROMP) catalyst followed by norbornene to produce flexible, stable composite materials in which poly(norbornene) is covalently attached to the porous Si matrix.

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