• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

Highly regioselective ring opening of oxiranes with phenoxides in the presence of beta-cyclodextrin in water.

作者信息

Surendra K, Krishnaveni N Srilakshmi, Nageswar Y V D, Rao K Rama

机构信息

Organic Chemistry Division I, Indian Institute of Chemical Technology, Hyderabad 500 007, India.

出版信息

J Org Chem. 2003 Jun 13;68(12):4994-5. doi: 10.1021/jo034194n.

DOI:10.1021/jo034194n
PMID:12790620
Abstract

Highly regioselective ring opening of oxiranes to beta-hydroxy ethers with phenoxides has been achieved in impressive yields in the presence of beta-cyclodextrin as catalyst and water as solvent.

摘要

相似文献

1
Highly regioselective ring opening of oxiranes with phenoxides in the presence of beta-cyclodextrin in water.
J Org Chem. 2003 Jun 13;68(12):4994-5. doi: 10.1021/jo034194n.
2
Facile ring-opening of oxiranes by H(2)O(2) catalyzed by phosphomolybdic acid.磷钼酸催化过氧化氢使环氧乙烷容易开环。
Org Lett. 2009 Jun 18;11(12):2691-4. doi: 10.1021/ol900811m.
3
Formal total synthesis of (+)-lysergic acid via zinc(II)-mediated regioselective ring-opening reduction of 2-alkynyl-3-indolyloxirane.通过锌(II)介导的 2-炔基-3-吲哚环氧开环区域选择性还原反应实现(+)-麦角酸的全合成。
J Org Chem. 2011 Jul 1;76(13):5506-12. doi: 10.1021/jo2008324. Epub 2011 Jun 8.
4
Isolation of the key intermediates in the catalyst-free conversion of oxiranes to thiiranes in water at ambient temperature.
Org Biomol Chem. 2009 Apr 7;7(7):1397-403. doi: 10.1039/b820232j. Epub 2009 Feb 25.
5
Regioselective and stereospecific cleavage of a terminal oxirane system: a novel synthetic approach to lipid mediator congeners--1,2(2,3)-diacyl-3(1)-halo-sn-glycerols.末端环氧乙烷体系的区域选择性和立体特异性裂解:一种合成脂质介质同系物——1,2(2,3)-二酰基-3(1)-卤代-sn-甘油的新方法。
Bioorg Med Chem Lett. 2006 Jul 1;16(13):3388-91. doi: 10.1016/j.bmcl.2006.04.040. Epub 2006 May 3.
6
Trisubstituted aziridine ring-opening by phenol derivatives: stereo- and regioselective formation of chiral tertiary alkyl-aryl ethers.苯酚衍生物引发的三取代氮杂环丙烷开环反应:手性叔烷基-芳基醚的立体和区域选择性形成
Org Lett. 2006 Oct 26;8(22):5105-7. doi: 10.1021/ol062010w.
7
Highly regioselective Lewis acid-catalyzed [3+2] cycloaddition of alkynes with donor-acceptor oxiranes by selective carbon-carbon bond cleavage of epoxides.高区域选择性路易斯酸催化的炔烃与给体-受体环氧乙烷的[3+2]环加成反应,通过环氧乙烷的选择性碳-碳键断裂实现。
Chem Commun (Camb). 2011 Dec 28;47(48):12870-2. doi: 10.1039/c1cc15669a. Epub 2011 Nov 9.
8
Functionalization of cyclodextrins via reactions of 2,3-anhydrocyclodextrins.通过2,3-脱水环糊精反应实现环糊精的功能化
J Org Chem. 2003 Nov 28;68(24):9456-66. doi: 10.1021/jo035229m.
9
Stereoselective synthesis of azetidines and pyrrolidines from N-tert-butylsulfonyl(2-aminoalkyl)oxiranes.从N-叔丁基磺酰基(2-氨基烷基)环氧乙烷立体选择性合成氮杂环丁烷和吡咯烷。
J Org Chem. 2009 Oct 16;74(20):7859-65. doi: 10.1021/jo9016666.
10
Supramolecular catalysis of Strecker reaction in water under neutral conditions in the presence of beta-cyclodextrin.在β-环糊精存在下,水相中中性条件下斯特雷克反应的超分子催化作用。
J Org Chem. 2006 Mar 17;71(6):2532-4. doi: 10.1021/jo052510n.

引用本文的文献

1
Mechanochemical synthesis of unsymmetrical salens for the preparation of Co-salen complexes and their evaluation as catalysts for the synthesis of α-aryloxy alcohols via asymmetric phenolic kinetic resolution of terminal epoxides.用于制备钴-萨伦配合物的不对称萨伦的机械化学合成及其作为通过末端环氧化物的不对称酚醛动力学拆分合成α-芳氧基醇的催化剂的评估。
Beilstein J Org Chem. 2022 Oct 10;18:1416-1423. doi: 10.3762/bjoc.18.147. eCollection 2022.
2
High-efficiency dynamic sensing of biothiols in cancer cells with a fluorescent β-cyclodextrin supramolecular assembly.利用荧光β-环糊精超分子组装体对癌细胞中的生物硫醇进行高效动态传感
Chem Sci. 2020 Apr 22;11(18):4791-4800. doi: 10.1039/d0sc00414f.
3
Chiral epoxides via borane reduction of 2-haloketones catalyzed by spiroborate ester: application to the synthesis of optically pure 1,2-hydroxy ethers and 1,2-azido alcohols.
手性环氧化物通过螺环硼酸酯酯催化的 2-卤代酮的硼烷还原:在光学纯 1,2-羟基醚和 1,2-叠氮醇合成中的应用。
J Org Chem. 2011 Mar 18;76(6):1883-6. doi: 10.1021/jo102294j. Epub 2011 Feb 4.
4
Discovery, synthesis, and biological evaluation of piperidinol analogs with anti-tuberculosis activity.具有抗结核活性的哌啶醇类似物的发现、合成及生物学评价
Bioorg Med Chem. 2009 May 15;17(10):3588-94. doi: 10.1016/j.bmc.2009.04.005. Epub 2009 Apr 9.