通过扫描隧道显微镜探测二维超分子自组装
Two-dimensional supramolecular self-assembly probed by scanning tunneling microscopy.
作者信息
De Feyter Steven, De Schryver Frans C
机构信息
Katholieke Universiteit Leuven, Department of Chemistry, Celestijnenlaan 200 F, B-3001 Heverlee, Belgium.
出版信息
Chem Soc Rev. 2003 May;32(3):139-50. doi: 10.1039/b206566p.
Supramolecular chemistry has a very large impact on chemistry of current interest and the use of non-covalent but directional forces is appealing for the construction of 'supramolecular architectures'. The invention of scanning probe microscopy techniques has opened new doorways to study these concepts on surfaces. This review deals with recent progress in the study of two-dimensional supramolecular self-assembly on surfaces probed by scanning tunneling microscopy, with a special emphasis on structure, dynamics and reactivity of hydrogen bonded systems.
超分子化学对当前热门的化学领域有着巨大影响，利用非共价但具有方向性的作用力来构建“超分子结构”很有吸引力。扫描探针显微镜技术的发明为在表面研究这些概念打开了新的大门。本综述论述了利用扫描隧道显微镜探测表面二维超分子自组装研究的最新进展，特别强调了氢键体系的结构、动力学和反应活性。
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