Hess Corinna R, Juda Gregory A, Dooley David M, Amii Ricky N, Hill Michael G, Winkler Jay R, Gray Harry B
Beckman Institute, California Institute of Technology, Pasadena, California 91125, USA.
J Am Chem Soc. 2003 Jun 18;125(24):7156-7. doi: 10.1021/ja029538q.
Diethylaniline-terminated oligo(phenyl-ethynyl)-thiol (DEA-OPE-SH) wires on Au-bead electrodes facilitate electron tunneling to and from the deeply buried topaquinone (TPQ) cofactor in Arthrobacter globiformis amine oxidase (AGAO). Reversible cyclic voltammograms were observed when AGAO was adsorbed onto this DEA-OPE-SAu surface: the 2e-/2H+ reduction potential is -140 mV versus SCE.
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