碳-氢活化/硼化/氧化：一条一锅法合成带有邻位/对位导向基团的间位取代苯酚的统一路线。
C-H activation/borylation/oxidation: a one-pot unified route to meta-substituted phenols bearing ortho-/para-directing groups.
作者信息
Maleczka Robert E, Shi Feng, Holmes Daniel, Smith Milton R
机构信息
Department of Chemistry, Michigan State University, East Lansing, MI 48824, USA.
出版信息
J Am Chem Soc. 2003 Jul 2;125(26):7792-3. doi: 10.1021/ja0349857.
PMID:12822984
Abstract
An efficient one-pot C-H activation/borylation/oxidation protocol for the preparation of phenols is described. This method is particularly attractive for the generation of meta-substituted phenols bearing ortho-/para-directing groups, as such substrates are difficult to access by other phenol syntheses.
摘要
描述了一种用于制备苯酚的高效一锅法C-H活化/硼化/氧化方案。该方法对于生成带有邻位/对位导向基团的间位取代苯酚特别有吸引力，因为其他苯酚合成方法难以获得此类底物。
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