Lu Chang-Sheng, Zou Yang, Xie Jing-Li, Ni Zhao-Ping, Zhu Hui-Zheng, Meng Qing-Jin, Yao Yuan-Gen
Coordination Chemistry Institute, State Key Laboratory of Coordination Chemistry, Nanjing University, PR China.
Chem Pharm Bull (Tokyo). 2003 Jul;51(7):864-6. doi: 10.1248/cpb.51.864.
The complex of a derivative of beta-cyclodextrin, that is mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto sodium salt)]-beta-cyclodextrin (6-mnt-beta-CD), with titanocene (titanocene di[mono[6-deoxy-6-(2-butenedinitrile-2,3-dimercapto)]-beta-cyclodextrin], Cp2Ti[6-mnt-beta-CD]2) has been synthesized and characterized by IR spectroscopy, UV spectroscopy, elemental analysis, thermogravimetry, 1H- and 13C-NMR spectroscopy. The stoichiometry of the target molecule was determined by 1H-NMR spectroscopy and elemental analysis.
已合成了β-环糊精衍生物单[6-脱氧-6-(2-丁烯二腈-2,3-二巯基钠盐)]-β-环糊精(6-mnt-β-CD)与二茂钛(二茂钛二[单[6-脱氧-6-(2-丁烯二腈-2,3-二巯基)]-β-环糊精], Cp2Ti[6-mnt-β-CD]2)的配合物，并通过红外光谱、紫外光谱、元素分析、热重分析、1H-和13C-核磁共振光谱对其进行了表征。通过1H-核磁共振光谱和元素分析确定了目标分子的化学计量比。
