石蜡中的格拉布催化剂：一种用于烯烃复分解反应的空气稳定制剂。
Grubbs' catalyst in paraffin: an air-stable preparation for alkene metathesis.
作者信息
Taber Douglass F, Frankowski Kevin J
机构信息
Department of Chemistry and Biochemistry, University of Delaware, Newark, Delaware 19716, USA.
出版信息
J Org Chem. 2003 Jul 25;68(15):6047-8. doi: 10.1021/jo030005p.
PMID:12868947
Abstract
A homogeneous mixture of Grubbs' catalyst in paraffin wax was shown to catalyze three important types of metathesis reactions: ring-closing metathesis, alkene dimerization, and alkene cross-metathesis (e.g., 11 --> 13). This catalyst preparation demonstrated no loss in catalytic activity after 22 months of storage open to the air.
摘要
已证明格拉布催化剂在石蜡中的均匀混合物可催化三种重要类型的复分解反应
关环复分解反应、烯烃二聚反应和烯烃交叉复分解反应（例如，11→13）。这种催化剂制剂在露天存放22个月后催化活性没有损失。
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