Modified BINOL ligands in asymmetric catalysis.

作者信息

Chen Yu, Yekta Shahla, Yudin Andrei K

机构信息

Department of Chemistry, University of Toronto, Davenport Building, 80 St. George Street, Toronto, Ontario, M5S 3H6 Canada.

出版信息

Chem Rev. 2003 Aug;103(8):3155-212. doi: 10.1021/cr020025b.

DOI:10.1021/cr020025b

PMID:12914495

Abstract

摘要

相似文献

Modified BINOL ligands in asymmetric catalysis.

Chem Rev. 2003 Aug;103(8):3155-212. doi: 10.1021/cr020025b.

Catalytic asymmetric Michael reaction of beta-keto esters: effects of the linker heteroatom in linked-BINOL.β-酮酯的催化不对称迈克尔反应：连接型联萘酚中连接原子的影响

J Am Chem Soc. 2003 Dec 24;125(51):15837-45. doi: 10.1021/ja037635t.

Chiral zirconium catalysts using multidentate BINOL derivatives for catalytic enantioselective Mannich-type reactions; ligand optimization and approaches to elucidation of the catalyst structure.使用多齿联萘酚衍生物的手性锆催化剂用于催化对映选择性曼尼希型反应；配体优化及催化剂结构的解析方法

J Am Chem Soc. 2005 Nov 9;127(44):15528-35. doi: 10.1021/ja053524d.

Asymmetric hydrogenation of ketones using a ruthenium(II) catalyst containing BINOL-derived monodonor phosphorus-donor ligands.使用含有联萘酚衍生的单齿磷供体配体的钌（II）催化剂对酮进行不对称氢化反应。

Org Lett. 2004 Oct 28;6(22):4105-7. doi: 10.1021/ol0481840.

Helical triskelion monophosphites as ligands in asymmetric catalysis.螺旋形三聚亚磷酸酯作为不对称催化中的配体。

J Am Chem Soc. 2009 Mar 25;131(11):4136-42. doi: 10.1021/ja809297a.

Titanium-catalyzed enantioselective additions of alkyl groups to aldehydes: mechanistic studies and new concepts in asymmetric catalysis.钛催化的醛的烷基对映选择性加成：机理研究与不对称催化的新概念

Acc Chem Res. 2003 Oct;36(10):739-49. doi: 10.1021/ar0300219.

A modular design of ruthenium catalysts with diamine and BINOL-derived phosphinite ligands that are enantiomerically-matched for the effective asymmetric transfer hydrogenation of simple ketones.一种具有二胺和源自联萘酚的次膦酸酯配体的钌催化剂的模块化设计，这些配体对简单酮的有效不对称转移氢化反应具有对映体匹配性。

Chem Commun (Camb). 2005 Jun 28(24):3050-2. doi: 10.1039/b502123e. Epub 2005 May 6.

BINOL-derived phosphoramidites in asymmetric hydrogenation: can the presence of a functionality in the amino group influence the catalytic outcome?联萘酚衍生的亚磷酰胺在不对称氢化反应中的应用：氨基中官能团的存在会影响催化结果吗？

Chem Soc Rev. 2008 Apr;37(4):839-64. doi: 10.1039/b714519e. Epub 2008 Feb 18.

Direct asymmetric aldol reaction of aryl ketones with aryl aldehydes catalyzed by chiral BINOL-derived zincate catalyst.手性联萘酚衍生的锌酸盐催化剂催化芳基酮与芳基醛的直接不对称羟醛反应。

J Org Chem. 2008 Sep 19;73(18):7398-401. doi: 10.1021/jo801182n. Epub 2008 Aug 14.

Highly enantioselective phenylacetylene additions to ketones catalyzed by (S)-BINOL-Ti complex.由（S）-联萘酚-钛配合物催化的酮与苯乙炔的高度对映选择性加成反应。

Org Lett. 2004 Nov 11;6(23):4147-9. doi: 10.1021/ol0485621.

引用本文的文献

Enantioselective synthesis of C-C and C-N axially chiral pyrazole-based heterobiaryls.C-C和C-N轴手性吡唑基杂双芳基的对映选择性合成。

Chem Sci. 2025 Sep 23. doi: 10.1039/d5sc06841j.

Artificial Chiral Trinuclear Zn Catalysts: Design, Self-Assembly and Unprecedented Efficiency in Asymmetric Hydroboration of Ketones.人工手性三核锌催化剂：酮类不对称硼氢化反应中的设计、自组装及前所未有的效率

ACS Cent Sci. 2025 Aug 12;11(9):1773-1783. doi: 10.1021/acscentsci.5c01067. eCollection 2025 Sep 24.

Expedited Synthesis of Axially Chiral 3-Monosilyl and 3,3'-Bis-silyl Biphenols, Binaphthols, and Phosphoramidites Enabled by Catalytic Two-Fold C-H Silylation with a Traceless Acetal Directing Group.通过无痕缩醛导向基团催化的双C-H硅基化实现轴向手性3-单硅基和3,3'-双硅基联苯酚、联萘酚及磷酰胺的快速合成。

ACS Catal. 2025 Jan 17;15(2):967-975. doi: 10.1021/acscatal.4c05927. Epub 2024 Dec 31.

-TEtraQuinoline (-TEQ): an inherently chiral N4 macrocyclic quinoline tetramer.-四喹啉（-TEQ）：一种具有固有手性的N4大环喹啉四聚体。

Chem Sci. 2025 May 20;16(24):10714-10721. doi: 10.1039/d5sc02937f. eCollection 2025 Jun 18.

Synthesis and resolution of a 1,1'-biazulene analogue of BINOL.联萘酚（BINOL）的1,1'-双薁类似物的合成与拆分

RSC Adv. 2025 May 16;15(19):14881-14892. doi: 10.1039/d5ra02520f. eCollection 2025 May 6.

Bis-indole chiral architectures for asymmetric catalysis.用于不对称催化的双吲哚手性结构

Nat Commun. 2025 Apr 17;16(1):3676. doi: 10.1038/s41467-025-58313-4.

Enantioselective Ring Opening of Azetidines via Charge Recognition in Hydrogen-Bond-Donor Catalysis.通过氢键供体催化中的电荷识别实现氮杂环丁烷的对映选择性开环反应。

J Am Chem Soc. 2025 Feb 26;147(8):6378-6383. doi: 10.1021/jacs.5c00165. Epub 2025 Feb 17.

An unusual chiral-at-metal mechanism for BINOL-metal asymmetric catalysis.联萘酚-金属不对称催化中一种不同寻常的金属手性中心机制。

Nat Commun. 2025 Jan 16;16(1):735. doi: 10.1038/s41467-025-56000-y.

Overcoming the Limitations of Transition-Metal Catalysis in the Chemoenzymatic Dynamic Kinetic Resolution (DKR) of Atropisomeric Bisnaphthols.克服轴手性双萘酚化学酶法动态动力学拆分（DKR）中过渡金属催化的局限性

ACS Cent Sci. 2024 Nov 5;10(11):2099-2110. doi: 10.1021/acscentsci.4c01370. eCollection 2024 Nov 27.

Atroposelective synthesis of axially chiral imidazo[1,2-]pyridines via asymmetric multicomponent reaction.通过不对称多组分反应实现轴手性咪唑并[1,2 - ]吡啶的对映选择性合成。

Sci Adv. 2024 Dec 6;10(49):eadr6135. doi: 10.1126/sciadv.adr6135. Epub 2024 Dec 4.

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验