Acetylenic scaffolding on solid support: poly(triacetylene)-derived oligomers by Sonogashira and Cadiot-Chodkiewicz-type cross-coupling reactions.
作者信息
Utesch Nils F, Diederich François
机构信息
Laboratorium für Organische Chemie, ETH-Hönggerberg, HCI, CH-8093 Zürich, Switzerland.
出版信息
Org Biomol Chem. 2003 Jan 21;1(2):237-9. doi: 10.1039/b210184j.
DOI:10.1039/b210184j
PMID:12929415
Abstract
We report the first synthesis of poly(triacetylene)-derived oligomers by Pd(0)-catalysed Sonogashira and Cadiot-Chodkiewicz-type cross-coupling reactions on solid support. Oligo(phenylene triacetylene)s, members of a new class of linearly pi-conjugated oligomers with all-carbon backbones, feature very high fluorescence intensities.
摘要
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