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紫朱草素,一种来自紫花爵床的不寻常的裂环木脂素糖苷。

Juspurpurin, an unusual secolignan glycoside from Justicia purpurea.

作者信息

Kavitha Jakka, Gopalaiah Kovuru, Rajasekhar Dodda, Subbaraju Gottumukkala V

机构信息

Department of Chemistry, Sri Venkateswara University, Tirupati-517 502, India.

出版信息

J Nat Prod. 2003 Aug;66(8):1113-5. doi: 10.1021/np030142h.

Abstract

An unusual secolignan glycoside, juspurpurin (1), and a new arylnaphthalene glycoside, justalakonin (2), together with eight known lignans were isolated from the whole plants of Justicia purpurea. Compound 1 is the first glycoside of a rare group of secolignans. The structures of the new compounds 1 and 2 were established using 1D and 2D NMR ((1)H-(1)H COSY, HMQC, and HMBC) spectral data and by chemical transformations.

摘要

从紫花爵床全草中分离得到一种不寻常的裂环木脂素苷紫花爵床苷(1)、一种新的芳基萘苷紫花拉孔苷(2)以及8个已知木脂素。化合物1是一类罕见裂环木脂素中的首个糖苷。通过一维和二维核磁共振谱(氢氢化学位移相关谱、异核多量子相干谱和异核多键相关谱)数据以及化学转化确定了新化合物1和2的结构。

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