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[利用遥感傅里叶变换红外光谱法测量烟火药剂的燃烧温度]

[Combustion temperature measurement of pyrotechnic composition using remote sensing Fourier transform infrared spectrometry].

作者信息

Zhou Xin-li, Li Yan, Liu Zu-liang, Zhu Chang-jiang, Wang Jun-de, Lu Chun-xu

机构信息

School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2002 Oct;22(5):764-6.

Abstract

In this paper, combustion characterization of pyrotechnic composition is investigated using a remote sensing Fourier transform infrared spectrometry. The emission spectra have been recorded between 4,700 and 740 cm-1 with a spectral resolution of 4 cm-1. The combustion temperature can be determined remotely from spectral line intensity distribution of the fine structure of the emission fundamental band of gaseous products such as HF. The relationship between combustion temperature and combustion time has been given. Results show that there is a violent mutative temperature field with bigger temperature gradient near combustion surface. It reveals that the method of temperature measurement using remote sensing FTIR for flame temperature of unstable, violent and short time combustion on real time is a rapid, accurate and sensitive technique without interference the flame temperature field. Potential prospects of temperature measurement, gas product concentration measurement and combustion mechanism are also revealed.

摘要

本文利用遥感傅里叶变换红外光谱法研究了烟火药剂的燃烧特性。发射光谱在4700至740厘米-1之间记录,光谱分辨率为4厘米-1。燃烧温度可根据气态产物如HF发射基带精细结构的谱线强度分布进行远程测定。给出了燃烧温度与燃烧时间的关系。结果表明燃烧表面附近存在剧烈变化的温度场,温度梯度较大。结果表明,利用遥感傅里叶变换红外光谱实时测量不稳定、剧烈且燃烧时间短的火焰温度的方法是一种快速、准确且灵敏的技术,不会干扰火焰温度场。还揭示了温度测量、气体产物浓度测量及燃烧机理的潜在前景。

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