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[α,α'-二氧代乙烯酮环S,S-缩醛的紫外光谱研究]

[Study on ultraviolet spectra of alpha,alpha'-dioxoketene cyclic S,S-acetals].

作者信息

An Yue, Hu Jie-han, Zhu Zai-ming, Li Ji-ping

机构信息

Chemistry Department, Liaoning Normal University, Dalian 116029, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2002 Oct;22(5):822-4.

Abstract

The characteristics of ultraviolet spectra of five alpha,alpha'-dioxoketene cyclis,s,s-acetals (N,N-acetals) have been studied in different solvent, on the basis of last paper. And the character of ultraviolet spectra of sulfur-containing compounds and nitrogen-containing compound was compared in the same solvent, the changing rules with the change of chemical structure have been indicated. It is specially important that the character of such as this conjugated system was studied, however it almost did not do before. And the this can used in studies afterwards.

摘要

在前一篇论文的基础上,研究了五种α,α'-二氧代乙烯酮环二硫代缩醛(N,N-缩醛)在不同溶剂中的紫外光谱特征。并在相同溶剂中比较了含硫化合物和含氮化合物的紫外光谱特征,指出了其随化学结构变化的规律。特别重要的是研究了这样的共轭体系的特征,然而以前几乎没有做过。并且这可用于后续的研究。

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