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[The FTIR and DR-FTIR characterization of studies on the surface functionalization reactions of vinyl acetate-divinylbenzene copolymeric microspheres].

作者信息

Wang J, Guan Y P, Liu H Z

机构信息

Young Scientist Laboratory of Separation Science and Engineering, Institute of Chemical Metallurgy, Chinese Academy of Sciences, Beijing 100080, China.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2001 Oct;21(5):611-3.

PMID:12945309
Abstract

A series of vinyl acetate (VAc)-divinylbenzene (DVB) copolymeric microspheres were prepared by suspension copolymerization. The surface hydroxyl group onto the VAc-DVA copolymeric microspheres can be obtained by saponifiction reaction on their surface. By reaction between the reactive chorine group of a dye and the hydroxyl groups on the VAc-DVB copolymeric microspheres, cibacron blue F3G-A, as an affinity ligand, was covalently immobilized on the surface of the VAc-DVB copolymeric microspheres. The characterization of surface functionalizationed VAc-DVB copolymeric microspheres was studied by means of FTIR and diffuse reflectance FTIR spectroscopy. The results indicate that DR-FTIR spectra give out more detailed information of the modified microspheres' surface than FTIR spectra does.

摘要

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