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[微波场中荧光粉CaS:Eu2+的快速合成及荧光光谱]

[Rapid synthesis and fluorescent spectra of the phosphor CaS:Eu2+ in a microwave field].

作者信息

Zhang M, Li J, Yan C

机构信息

School of Chemical Engineering, Zhongshan University, 510275 Guangzhou.

出版信息

Guang Pu Xue Yu Guang Pu Fen Xi. 2001 Jun;21(3):304-7.

Abstract

In this paper, the phosphors with CaS as the host and doped with Eu2+ ion were synthesized in a microwave field at the first time. The influence of the different concentrations of Eu2+ ion on fluorescent properties of the phosphors CaS:Eu2+ was discussed. The experimental results of SEM show that the crystallite structures of the CaS:Eu2+ with different shapes (such as cubic, spherical and rod) and different crystal sizes (100-1,500 nm), for example, nano-scale, submicron-scale or micron-scale can be obtained when doping different concentrations of Eu2+ ion. The fluorescent intensity of the sphere phosphor CaS:Eu2+ is the strongest under the excitation at 254 nm.

摘要

本文首次在微波场中合成了以CaS为基质、掺杂Eu2+离子的荧光粉。讨论了不同浓度Eu2+离子对CaS:Eu2+荧光粉荧光性能的影响。扫描电子显微镜(SEM)实验结果表明,掺杂不同浓度的Eu2+离子时,可以获得具有不同形状(如立方、球形和棒状)和不同晶体尺寸(100-1500nm),例如纳米级、亚微米级或微米级的CaS:Eu2+微晶结构。球形荧光粉CaS:Eu2+在254nm激发下的荧光强度最强。

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