Liu Huibiao, Li Yuliang, Xiao Shengqiang, Gan Haiyang, Jiu Tonggang, Li Hongmei, Jiang Lei, Zhu Daoben, Yu Dapeng, Xiang Bin, Chen Yaofeng
Center for Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100080, P R China.
J Am Chem Soc. 2003 Sep 10;125(36):10794-5. doi: 10.1021/ja036697g.
The synthesis of anthracene (AN) nanowires and perylene (PY) nanorods on the basis of solid-phase organic reactions under controlled conditions is discussed, and the structures are confirmed by SEM, TEM, and XRD. The dimension-dependent emission properties of the AN nanowires and PY nanorods is observed. This approach is expected to form a new general route for the controlled morphosynthesis of organic molecular materials in restricted dimensions, with controlled size and shape, the solid-state physical properties of which are of great interest. It should have outstanding potential in providing customized 1D nanomaterials for a broad range of applications for molecule devices and nanoscience and is expected to be applicable other functionalized nanomaterials (i.e., organic, inorganic, and polymer).
讨论了在可控条件下基于固相有机反应合成蒽（AN）纳米线和苝（PY）纳米棒，并通过扫描电子显微镜（SEM）、透射电子显微镜（TEM）和X射线衍射（XRD）对其结构进行了确认。观察到了AN纳米线和PY纳米棒的尺寸依赖性发射特性。这种方法有望为受限尺寸下有机分子材料的可控形态合成形成一条新的通用路线，其尺寸和形状可控，固态物理性质备受关注。它在为分子器件和纳米科学的广泛应用提供定制的一维纳米材料方面应具有突出潜力，并且有望适用于其他功能化纳米材料（即有机、无机和聚合物）。
