Peng R, Tang B, Zeng Z, Yang X, Zhang Z
Department of Chemistry, Zhongshan University, 510275 Guangzhou.
Guang Pu Xue Yu Guang Pu Fen Xi. 2001 Feb;21(1):77-80.
This paper describes interference and background correction problem of direct determination of Pb, Zn and Cd in soil, sediment, plants, halobios and sea water by FAAS. With the improvement of limit of detection(L.O.D) of instrument, Pb, Zn and Cd in same environmental and biological samples can be analyzed directly by FAAS, but it is worth taking attention that there are quantities of elements which lead to background interference in air-ethyne flame, such as Al, Na, K Ca, Mg and Fe. Compare with no background correction, limit of detection using D2 lamp background correction is improved by 1.05-4.5 times, the recoveries and the relative standard deviation(R.S.D) are better, standard samples were also analyzed with satisfactory results.
本文描述了用火焰原子吸收光谱法(FAAS)直接测定土壤、沉积物、植物、海洋生物和海水中铅、锌和镉时的干扰及背景校正问题。随着仪器检测限的提高,相同环境和生物样品中的铅、锌和镉可直接用FAAS进行分析,但值得注意的是,在空气-乙炔火焰中有大量元素会导致背景干扰,如铝、钠、钾、钙、镁和铁。与不进行背景校正相比,使用氘灯背景校正时检测限提高了1.05 - 4.5倍,回收率和相对标准偏差(R.S.D)更好,对标准样品分析也获得了满意结果。