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Ellagitannin chemistry. Studies on the stability and reactivity of 2,4-HHDP-containing glucopyranose systems.

作者信息

Feldman Ken S, Iyer Malliga R, Liu Yanze

机构信息

Department of Chemistry, The Pennsylvania State University, University Park, Pennsylvania 16802, USA.

出版信息

J Org Chem. 2003 Sep 19;68(19):7433-8. doi: 10.1021/jo034495x.

Abstract

The synthesis of a 2,4-HHDP containing glucopyranose ellagitannin model system has been achieved. Attempts to prepare a related target bearing a 1,6 bridge led instead to the discovery of a likely strain-driven tautomerization to cyclohexadienone intermediates.

摘要

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