水溶液中脂肪族羟胺的氧化
Oxidation of aliphatic hydroxylamines in aqueous solutions.
作者信息
Beckett A H, Purkaystha A R, Morgan P H
出版信息
J Pharm Pharmacol. 1977 Jan;29(1):15-21. doi: 10.1111/j.2042-7158.1977.tb11230.x.
Abstract
The effects of pH, buffer constituents, duration of storage, presence of air, heavy metal ions, extracting solvents and various additives and cofactors on the aerial oxidation of some aliphatic primary and secondary hydroxylamines were investigated. Copper ions were particularly effective catalysts of the oxidation reaction. Conditions to minimize this transformation are described.
摘要
研究了pH值、缓冲成分、储存时间、空气的存在、重金属离子、萃取溶剂以及各种添加剂和辅助因子对一些脂肪族伯羟胺和仲羟胺气相氧化的影响。铜离子是氧化反应特别有效的催化剂。文中描述了使这种转化最小化的条件。
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