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从六角莲地下部分分离得到的两种黄酮醇苷,即六角莲苷C和六角莲苷D。

Two flavonol glycosides, hexandrasides C and D, from the underground parts of Vancouveria hexandra.

作者信息

Mizuno M, Kanie Y, Iinuma M, Tanaka T, Lang F A

机构信息

Department of Pharmacognosy, Gifu Pharmaceutical University, Japan.

出版信息

Phytochemistry. 1991;30(8):2765-8. doi: 10.1016/0031-9422(91)85141-l.

Abstract

In addition to four known glycosides, icariin, epimedin B, epimedosides A and E, two new glycosides of a flavonol with a gamma,gamma-dimethylallyl group were isolated from the underground parts of Vancouveria hexandra. The structures were determined to be des-O-methyl-anhydroicaritin 3-O-beta-D-xylopyranosyl(1----2)-alpha-L-rhamnopyranoside 7-O-beta-D-glucopyranosyl(1----2)-beta-D-glucopyranoside and anhydroicaritin 3-O-alpha-L-rhamnopyranosyl(1----3)-alpha-L-rhamnopyranoside 7-O-beta-D-glucopyranoside by means of spectral analysis.

摘要

除了四种已知的糖苷,淫羊藿苷、朝藿定B、淫羊藿苷A和淫羊藿苷E外,还从六角莲的地下部分分离出两种带有γ,γ-二甲基烯丙基的黄酮醇新糖苷。通过光谱分析确定其结构分别为去-O-甲基脱水淫羊藿素3-O-β-D-吡喃木糖基(1→2)-α-L-吡喃鼠李糖苷7-O-β-D-吡喃葡萄糖基(1→2)-β-D-吡喃葡萄糖苷和脱水淫羊藿素3-O-α-L-吡喃鼠李糖苷(1→3)-α-L-吡喃鼠李糖苷7-O-β-D-吡喃葡萄糖苷。

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