萜类化合物的微生物转化。III. 一些单萜和倍半萜的转化
Microbiological transformations of terpenes. III. Transformations of some mono- and sesqui-terpenes.
作者信息
PREMA B R, BHATTACHRYYA P K
出版信息
Appl Microbiol. 1962 Nov;10(6):529-31. doi: 10.1128/am.10.6.529-531.1962.
The action of Aspergillus niger on mono- and sesqui-terpenic hydrocarbons, such as carane, 3-carene, alpha-santalene, and humulene was studied in shake cultures. Carane, Delta3-carene, and humulene proved to be rather resistant to oxygenation by the experimental strain of A. niger. Carene yielded a hydroxyketone, C(10)H(14)O(2), in poor yields after prolonged fermentation. The sesqui-terpene hydrocarbon, alpha-santalene, was degraded mainly to an acid, tere-santalic acid. Two hydroxylated products were also obtained from alpha-santalene, viz., tere-santalol and an alcohol, C(15)H(24)O.
在摇瓶培养中研究了黑曲霉对单萜和倍半萜碳氢化合物（如蒈烷、3-蒈烯、α-檀香萜烯和葎草烯）的作用。结果表明，蒈烷、Δ3-蒈烯和葎草烯对黑曲霉实验菌株的氧化作用具有较强的抗性。经过长时间发酵后，蒈烯仅以较低产率生成一种羟基酮C(10)H(14)O(2)。倍半萜碳氢化合物α-檀香萜烯主要降解为一种酸，即对檀香酸。从α-檀香萜烯还得到了两种羟基化产物，即对檀香醇和一种醇C(15)H(24)O。
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