Efficient oxidative decarboxylation of carboxylic acids with sodium periodate catalyzed by supported manganese (III) porphyrin.
作者信息
Mirkhani Valiollah, Tangestaninejad Shahram, Moghadam Majid, Karimian Zohreh
机构信息
Department of Chemistry, Isfahan University, Isfahan 81744, Iran.
出版信息
Bioorg Med Chem Lett. 2003 Oct 20;13(20):3433-5. doi: 10.1016/s0960-894x(03)00749-2.
Abstract
Oxidative decarboxylation of carboxylic acids by a supported manganese (III) porphyrin was investigated. In the chemical system using 5,10,15,20-tetrakis(4-aminophenyl)porphyrinatomanganese (III) chloride supported on crosslinked chloromethylated polystyrene, [Mn(H(2)NTPP)-CMP], as catalyst, carboxylic acids are converted to the corresponding carbonyl compounds via oxidative decarboxylation with sodium periodate.
摘要
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