锰（III）席夫碱配合物催化高碘酸钠实现羧酸的快速高效氧化脱羧反应。
Rapid and efficient oxidative decarboxylation of carboxylic acids with sodium periodate catalyzed by manganese (III) Schiff base complexes.
作者信息
Mirkhani Valiollah, Tangestaninejad Shahram, Moghadam Majid, Moghbel Maryam
机构信息
Department of Chemistry, Isfahan University, Isfahan 81746-73441, Iran.
出版信息
Bioorg Med Chem. 2004 Mar 1;12(5):903-6. doi: 10.1016/j.bmc.2003.12.025.
PMID:14980602
Abstract
Rapid and efficient oxidative decarboxylatoin of alpha-aryl carboxylic acids was observed. In the chemical system containing Mn(III)-salophen complex as catalyst, carboxylic acids are converted efficiently to the corresponding carbonyl derivatives with sodium periodate. The ability of various Schiff base complexes in the oxidative decarboxylation of carboxylic acids was also investigated.
摘要
观察到α-芳基羧酸能快速且高效地进行氧化脱羧反应。在以Mn(III)-双水杨醛缩邻苯二胺络合物为催化剂的化学体系中，羧酸能与高碘酸钠高效地转化为相应的羰基衍生物。还研究了各种席夫碱络合物在羧酸氧化脱羧反应中的能力。
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