Ishida Yasuhiro, Amano Sayaka, Saigo Kazuhiko
Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, Hongo, Bunkyo-ku, Tokyo 113-8656, Japan.
Chem Commun (Camb). 2003 Sep 21(18):2338-9. doi: 10.1039/b305625b.
The salts of trialkoxybenzoic acids and 2-amino alcohols showed a columnar liquid crystalline phase; in the case of the salt of a polymerizable acid and norephedrine, the photopolymerization proceeded efficiently in the liquid crystalline state, and the resultant solid adsorbed 2-amino alcohols size, regio-, and enantio-selectively.
三烷氧基苯甲酸与2-氨基醇形成的盐呈现柱状液晶相；对于可聚合酸与去甲麻黄碱形成的盐，光聚合在液晶态下能高效进行，并且所得固体对2-氨基醇具有尺寸、区域和对映体选择性吸附。
