New method for synthesizing the intermediates to 5-HETE from yeast-mediated reduction products by employing Baeyer-Villiger oxidation with complete retention of enantiomeric excess.
作者信息
Yamauchi Satoshi, Kinoshita Yoshihiro, Kinoshita Yoshiro
机构信息
Faculty of Agriculture, Ehime University, Matsuyama, Japan.
出版信息
Biosci Biotechnol Biochem. 2003 Sep;67(9):1959-69. doi: 10.1271/bbb.67.1959.
PMID:14519982
Abstract
(R) and (S)-Aldehydes 2, which are intermediates for the synthesis of (5R) and (5S)-HETE, were respectively synthesized from the yeast-mediated reductive products, hydroxy ester 3 and cis-lactone 4, through Baeyer-Villiger oxidation with complete retention of enantiomeric excess.
摘要
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