重组全细胞生物催化剂对萜烯酮的微生物拜耳-维利格氧化——对映体互补区域异构体内酯的形成
Microbial Baeyer-Villiger oxidation of terpenones by recombinant whole-cell biocatalysts--formation of enantiocomplementary regioisomeric lactones.
作者信息
Cernuchová Petra, Mihovilovic Marko D
机构信息
Institute of Applied Synthetic Chemistry, Vienna University of Technology, Getreidemarkt 9/163-OC, 1060 Vienna, Austria.
出版信息
Org Biomol Chem. 2007 Jun 7;5(11):1715-9. doi: 10.1039/b703175k. Epub 2007 Apr 25.
DOI:10.1039/b703175k
PMID:17520139
Abstract
Recombinant whole-cell expression systems for Baeyer-Villiger monooxygenases of various bacterial origin were utilized in the regiodivergent biooxidation of cyclic terpenones enabling access to enantio- and regioisomeric lactones on preparative scale.
摘要
利用来自各种细菌来源的拜耳-维利格单加氧酶的重组全细胞表达系统，对环状萜烯酮进行区域发散性生物氧化，从而能够在制备规模上获得对映体和区域异构体内酯。
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