铑配合物催化的烯烃螯合辅助氢酯化反应
Chelation-assisted hydroesterification of alkenes catalyzed by rhodium complex.
作者信息
Yokota Kazuhiko, Tatamidani Hiroto, Fukumoto Yoshiya, Chatani Naoto
机构信息
Department of Applied Chemistry, Faculty of Engineering, Osaka University, Suita, Osaka 565-0871, Japan.
出版信息
Org Lett. 2003 Nov 13;5(23):4329-31. doi: 10.1021/ol035582e.
PMID:14601992
Abstract
[reaction: see text] The hydroesterification of alkenes with 2-pyridylmethanol (1) catalyzed by Rh(4)(CO)(12) is described. The reaction is accelerated by the presence of a pyridine ring in the alcohol 1. The reaction is applicable to various alkenes, both terminal and internal alkenes.
摘要
[反应：见正文] 描述了由Rh₄(CO)₁₂催化的烯烃与2-吡啶甲醇（1）的氢酯化反应。醇1中吡啶环的存在加速了该反应。该反应适用于各种烯烃，包括末端烯烃和内烯烃。
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