Dohle Wolfgang, Staubitz Anne, Knochel Paul
Department Chemie, Ludwig-Maximilians-Universität, Butenandtstrasse 5 - 13, Haus F, 81377 München, Germany.
Chemistry. 2003 Nov 7;9(21):5323-31. doi: 10.1002/chem.200305090.
Phenylmagnesium chloride has been used for the conversion of selected nitroarenes into nitrenes. Their insertion into a neighboring sp(2) C-H bond yielded functionalized heterocycles. A novel and mild synthesis of polyfunctional benzimidazoles and indoles is described.
苯基氯化镁已被用于将选定的硝基芳烃转化为氮烯。它们插入相邻的sp(2) C-H键生成了功能化杂环。本文描述了一种新型温和的多官能团苯并咪唑和吲哚的合成方法。
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